British troops blinded by poison gas during the Battle of Estaires, 1918

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The German army was the first to successfully deploy chemical weapons during the Second Battle of Ypres in 1915, after German scientists had developed a method to weaponize chlorine. The use of chemical weapons was sanctioned by the German High Command in an effort to force Allied soldiers out of their entrenched positions, complementing rather than replacing more lethal conventional weapons.

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In time, chemical weapons were deployed by all major sides throughout the war, inflicting approximately 1.3 million casualties, but relatively few fatalities: About 90,000 in total. For example, there were an estimated 186,000 British chemical weapons casualties during the war (80% of which were the result of exposure to the vesicant sulfur mustard, introduced to the battlefield by the Germans in July 1917, which burns the skin at any point of contact and inflicts more severe lung damage than chlorine or phosgene), and up to one-third of American casualties were caused by them. The Russian Army reportedly suffered roughly 500,000 chemical weapon casualties in World War I.

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The effect of poison gas was not limited to combatants. Civilians were at risk from the gases as winds blew the poison gases through their towns, and they rarely received warnings or alerts of potential danger. In addition to absent warning systems, civilians often did not have access to effective gas masks. An estimated 100,000–260,000 civilian casualties were caused by chemical weapons during the conflict and tens of thousands more (along with military personnel) died from scarring of the lungs, skin damage, and cerebral damage in the years after the conflict ended. Many commanders on both sides knew such weapons would cause major harm to civilians but nonetheless continued to use them.

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"My officers and I were aware that such weapons would cause harm to women and children living in nearby towns, as strong winds were common in the battlefront. However, because the weapon was to be directed against the enemy, none of us were overly concerned at all."

Field Marshal Sir Douglas Haig

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The war damaged chemistry's prestige in European societies, in particular the German variety. The use of chemical weapons in warfare was in direct violation of the 1899 Hague Declaration Concerning Asphyxiating Gases and the 1907 Hague Convention on Land Warfare, which prohibited their use.

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Source: Wikipedia